Poly[dimethanolbis[μ-5-(3-pyridyl)tetrazolato-κ2 N 2:N 5]copper(II)]
نویسنده
چکیده
In the crystal structure of the title complex, [Cu(C(6)H(4)N(5))(2)(CH(3)OH)(2)](n), the Cu(II) cation lies on an inversion center and is coordinated by four 5-(3-pyrid-yl)tetra-zolate anions and two methanol mol-ecules in an elongated distorted CuN(4)O(2) octa-hedral geometry. Each 5-(3-pyrid-yl)tetra-zolate anion bridges two Cu(II) cations, forming a two-dimensional polymeric complex with (4,4) network topology. In the crystal structure, the two-dimensional layers are connected by inter-molecular O-H⋯N hydrogen bonding, forming a three-dimensional supra-molecular architecture.
منابع مشابه
Diaqua[5-(2-pyridyl)tetrazolato-κ2 N 1,N 5]manganese(II)
The title compound, [Mn(C(6)H(4)N(5))(2)(H(2)O)(2)], was synthesized by the hydro-thermal reaction of Mn(NO(3))(2) with picolino-nitrile in the presence of NaN(3). The Mn atom lies on an inversion centre. The distorted octa-hedral Mn environment contains two planar trans-related N,N'-chelating 5-(2-pyrid-yl)-tetra-zolate ligands in the equatorial plane and two axial water mol-ecules. O-H⋯N hydr...
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